{4,4′-Dibromo-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}zinc(II)
نویسنده
چکیده
The title mononuclear zinc(II) complex, [Zn(C(17)H(14)Br(2)N(2)O(2))], possesses a crystallographically imposed C(2) axis. The Zn atom is four-coordinated by two O and two N atoms from two Schiff base ligands, forming a severely distorted square-planar geometry. The central C atom of the propyl group is disordered over two positions about the twofold axis.
منابع مشابه
Dichlorido-2κ2 Cl-{μ-6,6′-dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato-1κ4 O 1,N,N′,O 1′:2κ2 O 1,O 1′}copper(II)zinc(II)
In the title compound, [CuZnCl(2)(C(19)H(20)N(2)O(4))], the Cu(II) ion exhibits a slightly distorted square-planar coordination geometry defined by two N atoms and two O atoms of the 6,6'-dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolate Schiff base ligand. The Zn(II) ion is also four-coordinated by the two phenolate O atoms of the Schiff base ligand and by two cis-coordina...
متن کامل{4,4′-Dibromo-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}copper(II)
In the title compound, [Cu(C(16)H(12)Br(2)N(2)O(2))], the Cu(II) atom is coordinated in a slightly distorted square-planar geometry by two O and two N atoms of the tetra-dentate dianionic 4,4'-dibromo-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphen-olate Schiff base ligand.
متن کامل{μ-6,6′-Dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}trinitratocopper(II)samarium(III) acetone solvate
In the title complex, [CuSm(C(19)H(20)N(2)O(4))(NO(3))(3)]·CH(3)CO-CH(3), the Cu(II) atom is four-coordinated in a square-planar geometry by two O atoms and two N atoms of the deprotonated Schiff base. The Sm(III) atom is ten-coordinate, chelated by three nitrate groups and linked to the four O atoms of the deprotonated Schiff base.
متن کاملDiaqua-1κO,3κO-di-μ-cyanido-1:2κ2 N:C;2:3κ2 C:N-dicyanido-2κ2 C-bis{4,4′-dibromo-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolato}-1κ4 O,N,N′,O′;3κ4 O,N,N′,O′-1,3-diiron(III)-2-nickel(II)
The title compound, [Fe(2)Ni(C(17)H(14)Br(2)N(2)O(2))(2)(CN)(4)(H(2)O)(2)] or [{Fe(C(17)H(14)Br(2)N(2)O(2))(H(2)O)}(2)(μ-CN)(2){Ni(CN)(2)}], is iso-structural with its Mn(III)-containing analogue. Each Fe(III) atom is chelated by a Schiff base ligand via two N and two O atoms and is additionally coordinated by a water mol-ecule, forming a slightly distorted octa-hedral geometry. The two Fe(III)...
متن کاملDiaqua-1κO,3κO-di-μ-cyanido-1:2κ2 N:C;2:3κ2 C:N-dicyanido-2κ2 N-bis{4,4′-dibromo-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolato}-1κ4 O,N,N′,O′;3κ4 O,N,N′,O′-1,3-dimanganese(III)-2-nickel(II)
In the title compound, [Mn(2)Ni(C(17)H(14)Br(2)N(2)O(2))(2)(CN)(4)(H(2)O)(2)] or [{Mn(C(17)H(14)Br(2)N(2)O(2))(H(2)O)}(2)(μ-CN)(2){Ni(CN)(2)}], each Mn(III) atom is chelated by a Schiff base ligand via two N and two O atoms and is additionally coordinated by a water mol-ecule to give a slightly distorted octa-hedral geometry. Two such Mn(III) ions are linked by a square-planar Ni(CN)(4) unit, w...
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008